MersV1, Main, Exploration, bibRecord, 002826

2-Acetylpyridinium 3-amino-2-chloropyridinium tetrachloridocobaltate(II)

Identifieur interne : 002826 ( Main/Exploration ); précédent : 002825; suivant : 002827

2-Acetylpyridinium 3-amino-2-chloropyridinium tetrachloridocobaltate(II)

Auteurs : Ariel Adamski [Pologne] ; Violetta Patroniak [Pologne] ; Maciej Kubicki [Pologne]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.

RBID : PMC:2968359

Abstract

In the title complex, (C₅H₆ClN₂)(C₇H₈NO)[CoCl₄], the Co^II ions are tetrahedrally coordinated. The crystal structure is built from hydrogen-bonded centrosymmetric tetramers of tetrachloridocobaltate(II) dianions and 3-amino-2-chloropyridinium cations, additionally strengthened by significant π–π stacking of pyridinium rings [interplanar distance 3.389 (3) Å]. The tetramers are linked by N—H⋯Cl hydrogen bonds into chains; the second kind of cations, viz. 2-acetylpyridinium, are connected by N—H⋯Cl hydrogen bonds to both sides of the chain. The Co—Cl bond lengths in the dianion correlate with the number of hydrogen bonds accepted by the Cl atom. An intramolecular C—H⋯Cl interaction is also present.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968359

DOI: 10.1107/S1600536809000713
PubMed: 21581781
PubMed Central: 2968359

Affiliations:

Pologne

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<front><div type="abstract" xml:lang="en"><p>In the title complex, (C<sub>5</sub>
H<sub>6</sub>
ClN<sub>2</sub>
)(C<sub>7</sub>
H<sub>8</sub>
NO)[CoCl<sub>4</sub>
], the Co<sup>II</sup>
 ions are tetrahedrally coordinated. The crystal structure is built from hydrogen-bonded centrosymmetric tetramers of tetrachloridocobaltate(II) dianions and 3-amino-2-chloropyridinium cations, additionally strengthened by significant π–π stacking of pyridinium rings [interplanar distance 3.389 (3) Å]. The tetramers are linked by N—H⋯Cl hydrogen bonds into chains; the second kind of cations, <italic>viz.</italic>
 2-acetylpyridinium, are connected by N—H⋯Cl hydrogen bonds to both sides of the chain. The Co—Cl bond lengths in the dianion correlate with the number of hydrogen bonds accepted by the Cl atom. An intramolecular C—H⋯Cl interaction is also present.</p>
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2-Acetylpyridinium 3-amino-2-chloropyridinium tetrachloridocobaltate(II)

2-Acetylpyridinium 3-amino-2-chloropyridinium tetrachloridocobaltate(II)

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2-Acetyl­pyridinium 3-amino-2-chloro­pyridinium tetra­chloridocobaltate(II)

2-Acetyl­pyridinium 3-amino-2-chloro­pyridinium tetra­chloridocobaltate(II)

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2-Acetylpyridinium 3-amino-2-chloropyridinium tetrachloridocobaltate(II)

2-Acetylpyridinium 3-amino-2-chloropyridinium tetrachloridocobaltate(II)